Macroscopic and microscopic fields in high-resolution liquid NMR

被引:51
作者
Vlassenbroek, A
Jeener, J
Broekaert, P
机构
[1] Université Libre de Bruxelles, CPI-232, B-1050 Brussels, Boulevard du Triomphe
关键词
D O I
10.1006/jmra.1996.0032
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The microscopic magnetic-induction field ''seen by each nucleus'' in a material medium and which is generated by a rapidly time-dependent spin magnetization gives rise to surprising new features in high-resolution nuclear magnetic resonance experiments. The purpose of the present paper is to show how the relations between the macroscopic average fields, the magnetization, and the microscopic fields (which were studied and clarified long ago at thermal equilibrium) can be extended to the present NMR context in which the magnetization can become rapidly time dependent and unrelated to thermal equilibrium properties. (C) 1996 Academic Press, Inc.
引用
收藏
页码:234 / 246
页数:13
相关论文
共 18 条