Novel and catalytic oxidation of internal epoxides to α-diketones

被引:25
作者
Antoniotti, S
Duñach, E
机构
[1] Univ Nice, Chim Bioorgan Lab, CNRS, UMR 6001, F-06108 Nice 2, France
[2] Univ Nice, Lab Aromes Synth & Interact, F-06108 Nice 2, France
关键词
D O I
10.1039/b106110k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A catalytic system based on Bi(0)-Cu(OTf)(2) is efficient for the selective one-pot oxidation of 1,2-disubstituted epoxides to alpha -diketones under molecular oxygen and DMSO.
引用
收藏
页码:2566 / 2567
页数:2
相关论文
共 16 条
  • [1] OXIDATION OF VICINAL DIOLS TO ALPHA-DICARBONYL COMPOUNDS BY TRIFLUOROACETIC-ANHYDRIDE ACTIVATED DIMETHYLSULFOXIDE
    AMON, CM
    BANWELL, MG
    GRAVATT, GL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (22) : 4851 - 4855
  • [2] Bismuth(III) oxide perchlorate promoted rearrangement of epoxides to aldehydes and ketones
    Anderson, AM
    Blazek, JM
    Garg, P
    Payne, BJ
    Mohan, RS
    [J]. TETRAHEDRON LETTERS, 2000, 41 (10) : 1527 - 1530
  • [3] Coin C, 2001, EUR J ORG CHEM, V2001, P735, DOI 10.1002/1099-0690(200102)2001:4<735::AID-EJOC735>3.0.CO
  • [4] 2-E
  • [5] Enantioselective ring opening of epoxides with silicon tetrachloride in the presence of a chiral Lewis base
    Denmark, SE
    Barsanti, PA
    Wong, KT
    Stavenger, RA
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (08) : 2428 - 2429
  • [6] Irwing-Sax N., 1989, DANGEROUS PROPERTIES, P283
  • [7] Fluoro alcohol as reaction medium:: one-pot synthesis of β-hydroxy sulfoxides from epoxides
    Kesavan, V
    Bonnet-Delpon, D
    Bégué, JP
    [J]. TETRAHEDRON LETTERS, 2000, 41 (16) : 2895 - 2898
  • [8] A ruthenium-catalyzed, novel and facile procedure for the conversion of vicinal dihaloalkenes to α-diketones
    Khan, FA
    Prabhudas, B
    Dash, J
    Sahu, N
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (39) : 9558 - 9559
  • [9] A novel method for the deprotection of S,S-acetals using air and a catalytic amount of bismuth(III) nitrate
    Komatsu, N
    Taniguchi, A
    Uda, M
    Suzuki, H
    [J]. CHEMICAL COMMUNICATIONS, 1996, (15) : 1847 - 1848
  • [10] Catalytic enantioselective meso-epoxide ring opening reaction with phenolic oxygen nucleophile promoted by gallium heterobimetallic multifunctional complexes
    Matsunaga, S
    Das, J
    Roels, J
    Vogl, EM
    Yamamoto, N
    Iida, T
    Yamaguchi, K
    Shibasaki, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (10) : 2252 - 2260