High-Performance Solution-Processed Solar Cells and Ambipolar Behavior in Organic Field-Effect Transistors with Thienyl-BODIPY Scaffoldings

被引：229

作者：

Bura, Thomas ^{[1
]}

Leclerc, Nicolas ^{[2
]}

Fall, Sadiara ^{[3
]}

Leveque, Patrick ^{[3
]}

Heiser, Thomas ^{[3
]}

Retailleau, Pascal ^{[4
]}

Rihn, Sandra ^{[1
]}

Mirloup, Antoine ^{[1
]}

Ziessel, Raymond ^{[1
]}

机构：

[1] Ecole Europeenne Chim Polymeres & Mat, UMR 7515, CNRS, Lab Chim Mol & Spect Avancees LCOSA, F-67087 Strasbourg 02, France

[2] Univ Strasbourg, Ecole Europeenne Chim Polymeres & Mat, Lab Ingn Polymeres Hautes Technol, F-67087 Strasbourg, France

[3] Univ Strasbourg, CNRS, Inst Elect Solide & Syst, F-67037 Strasbourg, France

[4] CNRS, Inst Chim Subst Nat, Ctr Rech Gif, F-91198 Gif Sur Yvette, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 42期

关键词：

DYES; EFFICIENCY; CHEMISTRY; POLYMERS; DESIGN;

D O I：

10.1021/ja3072513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Green-absorbing dipyrromethene dyes engineered from bis-vinyl-thienyl modules are planar molecules, exhibiting strong absorption in the 713-724 nm range and displaying comparable electron and hole mobilities in thin films (maximum value 1 x 10(-3) cm(2)/(V.s)). Bulk heterojunction solar cells assembled with these dyes and a fullerene derivative (PC61BM) at a low ratio give a power conversion efficiency as high as 4.7%, with short-circuit current values of 14.2 mA/cm(2), open-circuit voltage of 0.7 V, and a broad external quantum efficiency ranging from 350 to 920 nm with a maximum value of 60%.

引用

页码：17404 / 17407

页数：4

共 32 条

[1] Chemistry of squaraine-derived materials: Near-IR dyes, low band gap systems, and cation sensors
Ajayaghosh, A
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (06) : 449 - 459
[2] Air-stable complementary-like circuits based on organic ambipolar transistors
Anthopoulos, Thomas D.
Setayesh, Sepas
Smits, Edsger
Colle, Michael
Cantatore, Eugenio
de Boer, Bert
Blom, Paul W. M.
de Leeuw, Dago M.
[J]. ADVANCED MATERIALS, 2006, 18 (14) : 1900 - +
[3] Self-Assembled Gelators for Organic Electronics
Babu, Sukumaran Santhosh
Prasanthkumar, Seelam
Ajayaghosh, Ayyappanpillai
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) : 1766 - 1776
[4] Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications
Beaujuge, Pierre M.
Frechet, Jean M. J.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) : 20009 - 20029
[5] Thermoresponsive fluorescent polymers based on a quaterthiophene-containing boron dipyrromethene (Bodipy) dyad dispersed in silicone rubber
Benniston, Andrew C.
Copley, Graeme
Harriman, Anthony
Ryan, Ruth
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (08) : 2601 - 2608
[6] Impact of the Alkyl Side Chains on the Optoelectronic Properties of a Series of Photovoltaic Low-Band-Gap Copolymers
Biniek, Laure
Fall, Sadiara
Chochos, Christos L.
Anokhin, Denis V.
Ivanov, Dimitri A.
Leclerc, Nicolas
Leveque, Patrick
Heiser, Thomas
[J]. MACROMOLECULES, 2010, 43 (23) : 9779 - 9786
[7] Processable Low-Bandgap Polymers for Photovoltaic Applications
Boudreault, Pierre-Luc T.
Najari, Ahmed
Leclerc, Mario
[J]. CHEMISTRY OF MATERIALS, 2011, 23 (03) : 456 - 469
[8] Efficient Solution-Processed Bulk Heterojunction Solar Cells by Antiparallel Supramolecular Arrangement of Dipolar Donor-Acceptor Dyes
Buerckstuemmer, Hannah
Tulyakova, Elena V.
Deppisch, Manuela
Lenze, Martin R.
Kronenberg, Nils M.
Gsaenger, Marcel
Stolte, Matthias
Meerholz, Klaus
Wuerthner, Frank
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (49) : 11628 - 11632
[9] Geometry Relaxation-Induced Large Stokes Shift in Red-Emitting Borondipyrromethenes (BODIPY) and Applications in Fluorescent Thiol Probes
Chen, Yinghui
Zhao, Jianzhang
Guo, Huimin
Xie, Lijuan
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (05) : 2192 - 2206
[10] Effects of the Molecular Weight and the Side-Chain Length on the Photovoltaic Performance of Dithienosilole/Thienopyrrolodione Copolymers
Chu, Ta-Ya
Lu, Jianping
Beaupre, Serge
Zhang, Yanguang
Pouliot, Jean-Remi
Zhou, Jiayun
Najari, Ahmed
Leclerc, Mario
Tao, Ye
[J]. ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (11) : 2345 - 2351

← 1 2 3 4 →