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Infrared signatures of the spin-Peierls transition in CuGeO3
被引:28
作者:
Damascelli, A
vanderMarel, D
Parmigiani, F
Dhalenne, G
Revcolevschi, A
机构:
[1] POLITECN MILAN, INFM, I-20133 MILAN, ITALY
[2] POLITECN MILAN, DIPARTIMENTO FIS, I-20133 MILAN, ITALY
[3] UNIV PARIS 11, CHIM SOLIDE LAB, F-91405 ORSAY, FRANCE
关键词:
D O I:
10.1103/PhysRevB.56.R11373
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
We investigated the infrared reflectivity of several Mg-and Si-substituted CuGeO3 single crystals. The temperature-dependent b-axis and c-axis optical response is reported. For T < T-SP we detected the activation of zone-boundary phonons along the b axis of the crystal on the pure sample and for 1% Mg and 0.7% Si concentrations. From a detailed analysis of the phonon parameters the redshift of the B-2u mode at 48 cm(-1) is observed and discussed in relation to the soft mode expected to drive the spin-Peierls phase transition in CuGeO3. Moreover, the polarization dependence of a magnetic excitation measured in transmission at 44 cm(-1) has been investigated. [S0163-1829(97)51942-4].
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页码:11373 / 11376
页数:4
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