Electron impact dissociative excitation of water within the adiabatic nuclei approximation

被引：86

作者：

Gorfinkiel, JD ^{[1
]}

Morgan, LA ^{[1
]}

Tennyson, J ^{[1
]}

机构：

[1] UCL, Dept Phys & Astron, London WC1E 6BT, England

来源：

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 2002年 / 35卷 / 03期

关键词：

D O I：

10.1088/0953-4075/35/3/309

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The R-matrix method is used to calculate dissociative excitation cross sections for the four lowest-lying electronically excited states of H2O in the energy range 5-15 eV. For the first time calculations are performed taking into account the nuclear motion by means of an adaptation of the adiabatic nuclei approximation. Cross sections are compared with previous and new fixed-nuclei results and also experiments. Resonance positions and widths are calculated for different geometries of the water molecule.

引用

页码：543 / 555

页数：13

共 45 条

[41] Photodissociation of water.: II.: Wave packet calculations for the photofragmentation of H2O and D2O in the (B)over-tilde band [J].