Electrochemical decomplexation of phosphine-pentacarbonyltungsten complexes: The phosphole case

被引：6

作者：

Yakhvarov, DG

Budnikova, YH

Huy, NHT

Ricard, L

Mathey, F

机构：

[1] RAS, Inst Organ & Phys Chem, Kazan 420088, Russia

[2] Ecole Polytech, DCPH, UMR CNRS 7653, Lab Heteroelements & Coordinac, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 08期

关键词：

D O I：

10.1021/om030671g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical reduction of phosphole P-W(CO)(5) complexes affords the free phospholes in good yields. This technique allows the decomplexation of a 2-ethoxy-4-keto-4,5-dilzydrophosphole, which has been characterized by X-ray crystal structure analysis of its P-sulfide.

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页码：1961 / 1964

页数：4

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