A study of the semiclassical initial value representation at short times

被引:53
作者
Ankerhold, J
Saltzer, M
Pollak, E
机构
[1] Univ Freiburg, Fak Phys, D-79104 Freiburg, Germany
[2] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel
关键词
D O I
10.1063/1.1458924
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The short time dynamics of the semiclassical initial value separation are studied analytically for a one dimensional system. We find that at short times the approximation introduces spurious errors that depend on h and result from the anharmonic part of the potential. This is in contrast to classical mechanics which gives the first three initial time derivatives of a coordinate dependent operator exactly. Consideration of a model system shows, though, that the error introduced is not very large and that for times which are longer than a typical period of classical motion, semiclassical initial value representation propagation is superior to classical time propagation. (C) 2002 American Institute of Physics.
引用
收藏
页码:5925 / 5932
页数:8
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