Ultratough Artificial Nacre Based on Conjugated Cross-linked Graphene Oxide

被引:306
作者
Cheng, Qunfeng [1 ]
Wu, Mengxi [1 ]
Li, Mingzhu [2 ]
Jiang, Lei [1 ]
Tang, Zhiyong [3 ]
机构
[1] BeiHang Univ, Sch Chem & Environm, Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, Inst Chem, New Mat Lab, Beijing 100190, Peoples R China
[3] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
artificial nacre; cross-linking; graphene oxide; ultratough materials; MECHANICAL-PROPERTIES; NEXT-GENERATION; COMPOSITE FILMS; STRENGTH; NANOCOMPOSITES; DEFORMATION; TRANSPARENT; ULTRASTRONG; FABRICATION; REDUCTION;
D O I
10.1002/anie.201210166
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Inspired by natural nacre, layered composites based on graphene oxide (GO) and 10,12-pentacosadiyn-1-ol (PCDO) have been successfully fabricated. PCDO molecules are grafted onto GO sheets and cross-linked with each other, resulting in a superior toughness that is two times higher than that of the natural nacre. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3750 / 3755
页数:6
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