Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions

被引：138

作者：

Fu, Y

Xie, JH

Hu, AG

Zhou, H

Wang, LX

Zhou, QL

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 05期

关键词：

D O I：

10.1039/b109827f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel monodentate phosphorus ligands containing the 1,1 spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).

引用

页码：480 / 481

页数：2

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