Perfluorocarbon-hydrocarbon self-assembly -: Part 16.: 19F NMR study of the halogen bonding between halo-perfluorocarbons and heteroatom containing hydrocarbons

被引：134

作者：

Metrangolo, P

Panzeri, W

Recupero, F

Resnati, G

机构：

[1] Politecn Milan, Dept Chem, I-20131 Milan, Italy

[2] CNR, Ctr Studio Sostanze Organ Nat, I-20131 Milan, Italy

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 114卷 / 01期

关键词：

fluorine; nuclear magnetic resonance; noncovalent interactions; halogen bonding; supramolecular chemistry;

D O I：

10.1016/S0022-1139(01)00558-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The halogen bonding between structurally different halo-perfluorocarbons (R-f-X, R-f = aliphatic or aromatic perfluorinated residue, X = 1, Br, Cl) and heteroatom containing hydrocarbons (HC-D, HC = hydrocarbon residue, D = electron donor heteroatom) results in the formation of R-f-(XD)-D-...-HC complexes in the liquid phase. This formation strongly affects the F-19 NMR spectra of the perfluorinated partners. The Deltadelta(-CF2X),X and the Deltadelta(-CF=CX-) values of perfluoroalkyl and aryl derivatives is proven to be a simple, powerful, and versatile tool to rank the tendency of perfluorocarbon and HC modules to be involved in halogen bonding formation. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：27 / 33

页数：7

共 58 条

[41] The nature and geometry of intermolecular interactions between halogens and oxygen or nitrogen [J].