Effects of crystal shape on the energy levels of zero-dimensional PbS quantum dots

被引:73
作者
Hens, Z
Vanmaekelbergh, D
Stoffels, EJAJ
van Kempen, H
机构
[1] Univ Utrecht, Debye Inst, NL-3508 TA Utrecht, Netherlands
[2] Univ Nijmegen, Inst Mat Res, NL-6525 ED Nijmegen, Netherlands
关键词
Energy level spectra;
D O I
10.1103/PhysRevLett.88.236803
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Nanometer-size PbS quantum dots have been made by electrodeposition on a Au(111) substrate. The deposited nanocrystals have a flattened cubic shape. We probed the single-electron energy-level spectrum of individual quantum dots by scanning tunneling spectroscopy and found that it deviates strongly from that of spherical PbS quantum dots. The measured energy-level spectrum is successfully explained by considering strong confinement in a flattened cubic box.
引用
收藏
页码:2368031 / 2368034
页数:4
相关论文
共 15 条
[1]   Shell-tunneling Spectroscopy of the single-particle energy levels of insulating quantum dots [J].
Bakkers, EPAM ;
Hens, Z ;
Zunger, A ;
Franceschetti, A ;
Kouwenhoven, LP ;
Gurevich, L ;
Vanmaekelbergh, D .
NANO LETTERS, 2001, 1 (10) :551-556
[2]   Resonant electron tunneling through semiconducting nanocrystals in a symmetrical and an asymmetrical junction [J].
Bakkers, EPAM ;
Vanmaekelbergh, D .
PHYSICAL REVIEW B, 2000, 62 (12) :R7743-R7746
[3]   Identification of atomic-like electronic states in indium arsenide nanocrystal quantum dots [J].
Banin, U ;
Cao, YW ;
Katz, D ;
Millo, O .
NATURE, 1999, 400 (6744) :542-544
[4]   Shape and dielectric mismatch effects in semiconductor quantum dots [J].
Bolcatto, PG ;
Proetto, CR .
PHYSICAL REVIEW B, 1999, 59 (19) :12487-12498
[6]  
Franceschetti A, 2000, J PHYS CHEM B, V104, P3398, DOI 10.1021/jp000026
[7]   Imaging the wave-function amplitudes in cleaved semiconductor quantum boxes [J].
Grandidier, B ;
Niquet, YM ;
Legrand, B ;
Nys, JP ;
Priester, C ;
Stiévenard, D ;
Gérard, JM ;
Thierry-Mieg, V .
PHYSICAL REVIEW LETTERS, 2000, 85 (05) :1068-1071
[8]   Linearly polarized emission from colloidal semiconductor quantum rods [J].
Hu, JT ;
Li, LS ;
Yang, WD ;
Manna, L ;
Wang, LW ;
Alivisatos, AP .
SCIENCE, 2001, 292 (5524) :2060-2063
[9]   Electronic structure and optical properties of PbS and PbSe quantum dots [J].
Kang, I ;
Wise, FW .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1997, 14 (07) :1632-1646
[10]   Co deposition on Au(111) and Au(100) electrodes: an in situ STM study [J].
Kleinert, M ;
Waibel, HF ;
Engelmann, GE ;
Martin, H ;
Kolb, DM .
ELECTROCHIMICA ACTA, 2001, 46 (20-21) :3129-3136