Kinetic simulation of methane hydrate formation and dissociation in porous media

The vast amount of hydrocarbon gas deposited in the earth's crust as gas hydrates has significant implications for future energy supply and global climate. A 3-D simulator for methane hydrate formation and dissociation in porous media is developed for designing and interpreting laboratory and field hydrate experiments. Four components (hydrate, methane, water and salt) and five phases (hydrate, gas, aqueous-phase, ice and salt precipitate) are considered in the simulator. The intrinsic kinetics of hydrate formation or dissociation is considered using the Kim-Bishnoi model. Water freezing and ice melting are tracked with primary variable switch method (PVSM) by assuming equilibrium phase transition. Mass transport, including two-phase flow and molecular diffusions, and heat transfer involved in formation or dissociation of hydrates are included in the governing equations, which are discretized with finite volume difference method and are solved in a fully implicit manner. The developed simulator is used here to study the formation and the dissociation of hydrates in laboratory-scale core samples. In hydrate formation from the system of gas and ice (G + I) and in hydrate dissociation systems where ice appears, the equilibrium between aqueous-phase and ice (A-I) is found to have a "blocking" effect on heat transfer when salt is absent from the system. Increase of initial temperature (at constant outlet pressure), introduction of salt component into the system, decrease of outlet pressure, and increase of boundary heat transfer coefficient can lead to faster hydrate dissociation. (c) 2006 Elsevier Ltd. All rights reserved.