A pentacyclic aromatic lactam building block for efficient polymer solar cells

被引:143
作者
Cao, Jiamin [1 ,2 ]
Liao, Qiaogan [1 ]
Du, Xiaoyan [1 ,2 ]
Chen, Jianhua [1 ]
Xiao, Zuo [1 ]
Zuo, Qiqun [3 ]
Ding, Liming [1 ]
机构
[1] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Jiahong Optoelect, Suzhou 215151, Peoples R China
基金
中国国家自然科学基金;
关键词
POWER-CONVERSION EFFICIENCY; FIELD-EFFECT TRANSISTORS; HIGHLY EFFICIENT; ORGANIC PHOTOVOLTAICS; CONJUGATED POLYMERS; PERFORMANCE; BANDGAP; COPOLYMERS; DONOR; ABSORPTION;
D O I
10.1039/c3ee41948g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A D-A conjugated polymer (PThTPTI) was developed by using a brand new pentacyclic aromatic lactam acceptor unit (TPTI). PThTPTI possesses good light absorption, thermal stability, and a deep HOMO level. PThTPTI/PC71BM cells afford an outstanding PCE up to 7.80%, with high V-oc (0.87 V), J(sc) (13.69 mA cm(-2)) and FF (65.6%), and over 70% EQE in the range of 435-640 nm.
引用
收藏
页码:3224 / 3228
页数:5
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