(-)-cis-Pinononic acid: Hydrogen-bonding pattern of a delta-keto acid

被引：15

作者：

Cote, ML

Thompson, HW

Lalancette, RA

机构：

[1] Rutgers Univ, Newark

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270196012103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, (-)-cis-3-acetyl-2,2-dimethyl-cyclobutanecarboxylic acid, C9H14O3, carboxy-to-ketone chains (catemers) are formed between screw-related molecules spiraling along the b cell axis, with an O-H ... O distance of 2.747 (3) Angstrom. The carboxyl C=O group is not involved in the hydrogen bonding, although its O atom has a close contact 2.51 (5) Angstrom to a methyl H atom of a neighboring molecule.

引用

收藏

页码：102 / 106

页数：5

相关论文

共 22 条

[11] POTASSIUM-PERMANGANATE OXIDATIONS OF TERMINAL OLEFINS AND ACETYLENES TO CARBOXYLIC-ACIDS OF ONE LESS CARBON [J].

KRAPCHO, AP ;

LARSON, JR ;

ELDRIDGE, JM .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (23) :3749-3753

[12] MOLECULAR PACKING MODES - CARBOXYLIC-ACIDS [J].

LEISEROWITZ, L .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (MAR15) :775-802

[13] STRUCTURE OF CYCLOPROPANE AND CYCLOBUTANE FROM PROTON NUCLEAR MAGNETIC RESONANCE IN A NEMATIC SOLVENT [J].

MEIBOOM, S ;

SNYDER, LC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (04) :1038-&

[14] STRUCTURE AND DYNAMICS OF INTRAMOLECULAR HYDROGEN-BONDS IN CARBOXYLIC-ACID DIMERS - A SOLID-STATE NMR-STUDY [J].

MEIER, BH ;

GRAF, F ;

ERNST, RR .

JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (02) :767-774

[15] AN NMR RELAXATION STUDY ON THE PROTON-TRANSFER IN THE HYDROGEN-BONDED CARBOXYLIC-ACID DIMERS [J].

NAGAOKA, S ;

TERAO, T ;

IMASHIRO, F ;

SAIKA, A ;

HIROTA, N ;

HAYASHI, S .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (10) :4694-4703

[16]

SHELDRICK GM, 1994, SHELXTLIPC VERSION 5

[17]

TANABE M, 1967, TETRAHEDRON LETT, P3943

[18] 2-carboxy- and 2,7-dicarboxy-4,5-benzotropone: Hydrogen-bonding patterns of a beta-keto acid and a related beta-keto 1,5-diacid [J].

Thompson, HW ;

Lalancette, RA ;

Cote, ML .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1996, 52 :2372-2376

[19] 9-OXOBICYCLO[3.3.1]NONANE-1-CARBOXYLIC ACID - STRUCTURE AND HYDROGEN-BONDING PATTERN [J].

THOMPSON, HW ;

LALANCETTE, RA ;

VANDERHOFF, PA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :66-70

[20] STRUCTURE OF (+/-)-CIS-PINONIC ACID [J].

VANDERHOFF, PA ;

THOMPSON, HW ;

LALANCETTE, RA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :1766-1769