Electrochemiluminescence Resonance Energy Transfer Based on Ru(phen)32+-Doped Silica Nanoparticles and Its Application in "Turnon" Detection of Ozone

被引：73

作者：

Qi, Wenjing ^{[1
,2
]}

Wu, Di ^{[3
]}

Zhao, Jianming ^{[1
,2
]}

Liu, Zhongyuan ^{[1
]}

Zhang, Wei ^{[1
]}

Zhang, Ling ^{[1
,2
]}

Xu, Guobao ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Electroanalyt Chem, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China

[2] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Sichuan Univ Arts & Sci, Sichuan Key Lab Characterist Plant Dev Res, Dept Chem & Chem Engn, Dazhou 635000, Sichuan, Peoples R China

来源：

ANALYTICAL CHEMISTRY | 2013年 / 85卷 / 06期

基金：

中国国家自然科学基金;

关键词：

ELECTROGENERATED CHEMILUMINESCENCE; DNA; PROBE;

D O I：

10.1021/ac303533m

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Both the electrochemiluminescence (ECL) method for sensitive detection of ozone and the ECL resonance energy transfer (ECRET) using ozone have been reported for the first time. It is based on the ECRET of Ru(phen)(3)(2+)-doped silica nanoparticles (RuSiNPs) to indigo carmine. In the absence of ozone, the ECL of RuSiNPs is quenched as a result of the EGRET of RuSiNPs to indigo carmine. In the presence of ozone, the ECL of the system is "turned on" because ozone can oxidize indigo carmine and interrupt the ECRET from RuSiNPs to indigo carmine. In this way, it provides a simple ECL sensing of ozone via the proposed RuSiNP-based ECRET strategy with a linear range from 0.05-3.0 mu M and a limit of detection (LOD) of 30 nM. The detection takes less than 5 min. This method is also successfully applied in the analysis of ozone in human serum samples and atmospheric samples.

引用

页码：3207 / 3212

页数：6

共 26 条

[21] ELECTROGENERATED CHEMILUMINESCENCE .13. ELECTROCHEMICAL AND ELECTROGENERATED CHEMILUMINESCENCE STUDIES OF RUTHENIUM CHELATES [J].