Synthesis of Graphite Nanosheets/Polyaniline Nanorods Composites with Ultrasonic and Conductivity

被引:25
作者
Mo, Zunli [1 ]
Shi, Huafeng [1 ]
Chen, Hong [1 ]
Niu, Guiping [1 ]
Zhao, Zhongli [1 ]
Wu, Yingbing [1 ]
机构
[1] NW Normal Univ, Gansu Key Lab Polymer Mat, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
关键词
conducting polymers; nanocomposites; thermogravimetric analysis; NANOSHEET COMPOSITE; POLYANILINE; NANOCOMPOSITES; POLYMERIZATION; OXIDE;
D O I
10.1002/app.29411
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The graphite nanosheets/polyaniline (GN/PANI) nanorods composites were fabricated via ultrasonic polymerization of aniline monomer in the presence of GN, which was used as electric filling. The kind of doped acids, the concentration, and the contents of the GN were used as impact factors to the conductivity of the materials that were investigated. The structure of nanocomposites were characterized by FTIR and SEM. The results Show that ultrasonic can effectively restrain the agglomerate of the aniline and come to uniformity nanorods composites. The conductivity reached to 4.8 S/cm and 22 S/cm, respectively. The thermal stability of GN/PANI nanorods composites is superior to pure PANI as shown by TG analysis. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 573-578, 2009
引用
收藏
页码:573 / 578
页数:6
相关论文
共 26 条
[1]   Preparation of polystyrene/graphite nanosheet composite [J].
Chen, GH ;
Wu, CL ;
Weng, WG ;
Wu, DJ ;
Yan, WL .
POLYMER, 2003, 44 (06) :1781-1784
[2]   PTC effect of polyethylene/foliated graphite nanocomposites [J].
Chen, GH ;
Lu, JR ;
Wu, DJ .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (18) :5041-5043
[3]   PMMA/graphite nanosheets composite and its conducting properties [J].
Chen, GH ;
Weng, WG ;
Wu, DJ ;
Wu, CL .
EUROPEAN POLYMER JOURNAL, 2003, 39 (12) :2329-2335
[4]   Preparation and characterization of graphite nanosheets from ultrasonic powdering technique [J].
Chen, GH ;
Weng, WG ;
Wu, DJ ;
Wu, CL ;
Lu, JR ;
Wang, PP ;
Chen, XF .
CARBON, 2004, 42 (04) :753-759
[5]   Effect of β-cyclodextrin on the solid-state synthesized polyaniline doped with hydrochloric acid [J].
Ding, Youjiang ;
Abdiryim, Tursun ;
An, Shuying ;
Nurulla, Ismayil .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (06) :3864-3870
[6]   Facile synthesis of highly conductive polyaniline/graphite nanocomposites [J].
Du, XS ;
Xiao, M ;
Meng, YZ .
EUROPEAN POLYMER JOURNAL, 2004, 40 (07) :1489-1493
[7]   Synthesis and properties of poly (4,4′-oxybis (benzene)disulfide)/graphite nanocomposites via in situ ring-opening polymerization of macrocyclic oligomers [J].
Du, XS ;
Xiao, M ;
Meng, YZ ;
Hay, AS .
POLYMER, 2004, 45 (19) :6713-6718
[8]   Synthesis and characterization of polyaniline/graphite conducting nanocomposites [J].
Du, XS ;
Xiao, M ;
Meng, YZ .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (10) :1972-1978
[9]  
Fukuda K, 1997, J POWER SOURCES, V69, P165, DOI 10.1016/S0378-7753(97)02568-8
[10]   POLYANILINE - A HISTORICAL SURVEY [J].
GENIES, EM ;
BOYLE, A ;
LAPKOWSKI, M ;
TSINTAVIS, C .
SYNTHETIC METALS, 1990, 36 (02) :139-182