Suspended self-assembled opal membranes

被引:25
作者
Bohaty, Andrew K. [1 ]
Zharov, Ilya [1 ]
机构
[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
关键词
D O I
10.1021/la0602463
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Suspended self-assembled opal membranes have been prepared from 440- or 170-nm-diameter silica spheres by evaporation of their colloidal solutions over vertically oriented 0.3-mm-thick silicon wafers containing frustum-shaped openings. Robust 0.5 x 0.5 mm(2) membranes with a thickness of ca. 300 mu m have been reproducibly prepared using 170 nm silica spheres. The membranes show regular fcc packing with an exposed ( 111) orientation and are formed in a process that involves drawing silica spheres into the opening with the solvent meniscus.
引用
收藏
页码:5533 / 5536
页数:4
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