Recent developments in synthetic approaches to transition metal phosphide nanoparticles for magnetic and catalytic applications

被引：119

作者：

Brock, Stephanie L. ^{[1
]}

Senevirathne, Keerthi ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2008年 / 181卷 / 07期

基金：

美国国家科学基金会;

关键词：

metal phosphides; nanoparticle synthesis; size- and shape-dependent magnetic properties; hydrodesulfurization catalysis;

D O I：

10.1016/j.jssc.2008.03.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recent advances in synthetic methods have led to the preparation of a wide array of transition metal phosphide nanoparticles, and characterization of these materials has provided insight into nanoscale magnetic and catalytic properties. This review highlights advances in the field that have been made since the time of the last review [S.L. Brock, S.C. Perera, K.L. Stamm, Chem. Eur. J. 10(2004)3364-3371]. Synthetic methods include solvothermal, solution-phase arrested precipitation, metal nanoparticle conversion, and phosphate reduction. Magnetic properties of FeP, Fe2P and MnP nanoparticles and nanorods (among others), and recent data on thiophene hydrodesulfurization catalyzed by discrete, unsupported Ni2P particles, is presented. Finally, the future prospects for the field ate discussed. (C) 2008 Elsevier Inc. All rights reserved.

引用

页码：1552 / 1559

页数：8

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