Recent developments in synthetic approaches to transition metal phosphide nanoparticles for magnetic and catalytic applications

被引：119

作者：

Brock, Stephanie L. ^{[1
]}

Senevirathne, Keerthi ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2008年 / 181卷 / 07期

基金：

美国国家科学基金会;

关键词：

metal phosphides; nanoparticle synthesis; size- and shape-dependent magnetic properties; hydrodesulfurization catalysis;

D O I：

10.1016/j.jssc.2008.03.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recent advances in synthetic methods have led to the preparation of a wide array of transition metal phosphide nanoparticles, and characterization of these materials has provided insight into nanoscale magnetic and catalytic properties. This review highlights advances in the field that have been made since the time of the last review [S.L. Brock, S.C. Perera, K.L. Stamm, Chem. Eur. J. 10(2004)3364-3371]. Synthetic methods include solvothermal, solution-phase arrested precipitation, metal nanoparticle conversion, and phosphate reduction. Magnetic properties of FeP, Fe2P and MnP nanoparticles and nanorods (among others), and recent data on thiophene hydrodesulfurization catalyzed by discrete, unsupported Ni2P particles, is presented. Finally, the future prospects for the field ate discussed. (C) 2008 Elsevier Inc. All rights reserved.

引用

页码：1552 / 1559

页数：8

共 57 条

[41] Mechanisms of the shape evolution of CdSe nanocrystals [J].

Peng, ZA ;

Peng, XG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (07) :1389-1395

[42] Synthesis of MnP nanocrystals by treatment of metal carbonyl complexes with phosphines: A new, versatile route to nanoscale transition metal phosphides [J].

Perera, SC ;

Tsoi, G ;

Wenger, LE ;

Brock, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (46) :13960-13961

[43] Application of de-silylation strategies to the preparation of transition metal pnictide nanocrystals: The case of FeP [J].

Perera, SC ;

Fodor, PS ;

Tsoi, GM ;

Wenger, LE ;

Brock, SL .

CHEMISTRY OF MATERIALS, 2003, 15 (21) :4034-4038

[44] Solution-phase synthesis of single-crystalline iron phosphide nanorods/nanowires [J].

Qian, C ;

Kim, F ;

Ma, L ;

Tsui, F ;

Yang, PD ;

Liu, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (04) :1195-1198

[45] Thiophene hydrodesulfurization over nickel phosphide catalysts: effect of the precursor composition and support [J].

Sawhill, SJ ;

Layman, KA ;

Van Wyk, DR ;

Engelhard, MH ;

Wang, C ;

Bussell, ME .

JOURNAL OF CATALYSIS, 2005, 231 (02) :300-313

[46] Magnetism of Fe, Co and Ni nanowires in self-assembled arrays [J].

Sellmyer, DJ ;

Zheng, M ;

Skomski, R .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2001, 13 (25) :R433-R460

[47] Synthesis and characterization of discrete nickel phosphide nanoparticles: Effect of surface ligation chemistry on catalytic hydrodesulfurization of thiophene [J].

Senevirathne, Keerthi ;

Burns, Autumn W. ;

Bussell, Mark E. ;

Brock, Stephanie L. .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (18) :3933-3939

[48] Structure-sensitivity of hydrodesulfurization of 4,6-dimethyldibenzothiophene over silica-supported nickel phosphide catalysts [J].

Shu, YY ;

Lee, YK ;

Oyama, ST .

JOURNAL OF CATALYSIS, 2005, 236 (01) :112-121

[49] A new type of nonsulfide hydrotreating catalyst: nickel phosphide on carbon [J].

Shu, YY ;

Oyama, ST .

CHEMICAL COMMUNICATIONS, 2005, (09) :1143-1145

[50] A new route to prepare supported nickel phosphide/silica-alumina hydrotreating catalysts from amorphous alloys [J].

Song, Limin ;

Li, Wei ;

Wang, Guanglei ;

Zhang, Minghui ;

Tao, Keyi .

CATALYSIS TODAY, 2007, 125 (3-4) :137-142

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