The growing impact of titanocene(III)-mediated radical epoxide opening on the synthesis of natural products

被引：49

作者：

Cuerva, JM ^{[1
]}

Justicia, J ^{[1
]}

Oller-López, JL ^{[1
]}

Bazdi, B ^{[1
]}

Oltra, JE ^{[1
]}

机构：

[1] Univ Granada, Fac Ciencias, Dept Organ Chem, E-18071 Granada, Spain

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2006年 / 3卷 / 01期

关键词：

epoxides; titanocene; free radicals; synthetic methods; natural products;

D O I：

10.2174/157019306775474158

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review describes recent developments in the homolytic ring opening of epoxides mediated and catalysed by titanocene(III) complexes, with special emphasis on their applications for the synthesis of natural products.

引用

页码：23 / 35

页数：13

共 139 条

[91] INTERMOLECULAR RADICAL REACTIONS OF UNSATURATED CHROMIUM AND TUNGSTEN CARBENE COMPLEXES
MERLIC, CA
XU, DQ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (26) : 9855 - 9856
[92] STEREOCHEMISTRY OF INTERMOLECULAR RADICAL REACTIONS OF UNSATURATED TUNGSTEN CARBENE COMPLEXES
MERLIC, CA
XU, DQ
NGUYEN, MC
TRUONG, V
[J]. TETRAHEDRON LETTERS, 1993, 34 (02) : 227 - 230
[93] Mitsunobu O., 1991, COMPREHENSIVE ORGANI, V6, P1
[94] BIOLOGICALLY-ACTIVE LABDANE-TYPE DITERPENE GLYCOSIDES FROM THE ROOT-STALKS OF GLEICHENIA-JAPONICA
MUNESADA, K
SIDDIQUI, HL
SUGA, T
[J]. PHYTOCHEMISTRY, 1992, 31 (05) : 1533 - 1536
[95] Murai S, 1991, COMPREHENSIVE ORGANI, V8, P871, DOI DOI 10.1016/B978-0-08-052349-1.00249-3
[96] Stereo- and regio-selective Ti-mediated radical cyclization of epoxy-alkenes: synthesis of the A and C ring synthons of paclitaxel
Nakai, K
Kamoshita, M
Doi, T
Yamada, H
Takahashi, T
[J]. TETRAHEDRON LETTERS, 2001, 42 (44) : 7855 - 7857
[97] TRANSITION-METAL-CENTERED RADICALS IN ORGANIC-SYNTHESIS - TITANIUM(III)-INDUCED CYCLIZATION OF EPOXYOLEFINS
NUGENT, WA
RAJANBABU, TV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8561 - 8562
[98] OBRIEN ET, 1989, MOL PHARMACOL, V35, P635
[99] Preparation of α-C-glycosides from glycals
Parrish, JD
Little, RD
[J]. ORGANIC LETTERS, 2002, 4 (09) : 1439 - 1442
[100] SELECTIVE GENERATION OF FREE-RADICALS FROM EPOXIDES USING A TRANSITION-METAL RADICAL - A POWERFUL NEW TOOL FOR ORGANIC-SYNTHESIS
RAJANBABU, TV
NUGENT, WA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) : 986 - 997

← 5 6 7 8 9 10 11 12 13 14 →