A New Class of Pyrazolopyridine Nucleus with Fluorescent Properties, Obtained through Either a Radical or a Pd Arylation Pathway from N-Azinylpyridinium N-Aminides

被引：43

作者：

Abet, Valentina ^{[1
]}

Nunez, Araceli ^{[1
]}

Mendicuti, Francisco ^{[2
]}

Burgos, Carolina ^{[1
]}

Alvarez-Builla, Julio ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Quim Organ, Madrid 28871, Spain

[2] Univ Alcala de Henares, Dept Quim Fis, Madrid 28871, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 22期

关键词：

D O I：

10.1021/jo801549u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Chemical Equation Presented) The synthesis of dipyridopyrazole and pyridopyrazolopyrazine derivatives - both of which incorporate a 3-aryl moiety - can be achieved in moderate yields by intramolecular radical arylation of pyridinium N-aminides using tris(trimethylsilyl)silane and azobisisobutyronitrile. Improved results were obtained on using Pd direct arylation in conjunction with microwave irradiation. A preliminary study into the fluorescent properties of the target compounds is also reported. © 2008 American Chemical Society.

引用

页码：8800 / 8807

页数：8

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