Characterization of micro-mesoporous materials from nitrogen and toluene adsorption: Experiment and modeling

被引：72

作者：

Ravikovitch, PI

Vishnyakov, A

Neimark, AV

Carrott, MMLR

Russo, PA

Carrott, PJ

机构：

[1] TRI Princeton, Ctr Modeling & Characterizat Nanoporous Mat, Princeton, NJ 08540 USA

[2] Univ Evora, Dept Quim, P-7000671 Evora, Portugal

[3] Univ Evora, Ctr Quim Evora, P-7000671 Evora, Portugal

来源：

LANGMUIR | 2006年 / 22卷 / 02期

关键词：

D O I：

10.1021/la052202k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Universal mechanisms of adsorption and capillary condensation of toluene and nitrogen on ordered MCM-41 and PHTS materials are studied by means of high-resolution experiments and Monte Carlo molecular simulations. A molecular simulation model of toluene adsorption in silica nanopores, which accounts for surface heterogeneity, and a hybrid molecular-macsroscopic method for pore size distribution (PSD) calculations have been developed. For a range of reference materials, the PSD results obtained from toluene isotherms are consistent with the results of nitrogen adsorption using the nonlocal density functional theory method.

引用

收藏

页码：513 / 516

页数：4

相关论文

共 40 条

[1]

ALLEN MP, 1987, COMPUTER SIMLATION L

[2] Determination of pore size distribution in thin films by ellipsometric porosimetry [J].

Baklanov, MR ;

Mogilnikov, KP ;

Polovinkin, VG ;

Dultsev, FN .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2000, 18 (03) :1385-1391

[3] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[4] PHYSISORPTION OF ARGON, NITROGEN AND OXYGEN BY MCM-41, A MODEL MESOPOROUS ADSORBENT [J].

BRANTON, PJ ;

HALL, PG ;

SING, KSW ;

REICHERT, H ;

SCHUTH, F ;

UNGER, KK .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (19) :2965-2967

[5]

Carrott MMLR, 2001, MICROPOR MESOPOR MAT, V47, P323

[6] Experimental and computer simulation studies of the adsorption of ethane, carbon dioxide, and their binary mixtures in MCM-41 [J].

He, YF ;

Seaton, NA .

LANGMUIR, 2003, 19 (24) :10132-10138

[7] Adsorption study of surface and structural properties of MCM-41 materials of different pore sizes [J].

Kruk, M ;

Jaroniec, M ;

Sayari, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (04) :583-589

[8] Monte Carlo simulations of krypton adsorption in nanopores: Influence of pore-wall heterogeneity on the adsorption mechanism [J].

Kuchta, B ;

Llewellyn, P ;

Denoyel, R ;

Firlej, L .

LOW TEMPERATURE PHYSICS, 2003, 29 (9-10) :880-882

[9]

Lawson C.L., 1995, SIAM

[10] Structural characterization of porous low-k thin films prepared by different techniques using x-ray porosimetry [J].

Lee, HJ ;

Soles, CL ;

Liu, DW ;

Bauer, BJ ;

Lin, EK ;

Wu, WL ;

Grill, A .

JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2355-2359

← 1 2 3 4 →