A facile lipase catalyzed access to fatty acid monoesters of 2-O-beta-D-glucosylglycerol

被引：15

作者：

Colombo, D ^{[1
]}

Ronchetti, F ^{[1
]}

Scala, A ^{[1
]}

Taino, IM ^{[1
]}

Toma, L ^{[1
]}

机构：

[1] UNIV PAVIA,DIPARTIMENTO CHIM ORGAN,I-27100 PAVIA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 03期

关键词：

D O I：

10.1016/0957-4166(96)00073-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-O-beta-D-glucopyranosylglycerol was submitted to acylation using Pseudomonas cepacia lipase as catalyst and 2,2,2-trifluoroethyl esters of various long chain carboxylic acids as acyl carriers. Monoacylation was easily accomplished with preferred formation of the (2S)-1-O-acyl derivatives in reactions showing high regio- and diastereoselectivity. (C) 1996 Elsevier Science Ltd

引用

页码：771 / 777

页数：7

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