A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework

被引：747

作者：

Wan, Shun ^{[1
]}

Guo, Jia ^{[1
]}

Kim, Jangbae ^{[3
]}

Ihee, Hyotcherl ^{[3
]}

Jiang, Donglin ^{[1
,2
]}

机构：

[1] Inst Mol Sci Higashiyama, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan

[2] Japan Sci & Technol Agcy, Precursory Res Embryon Sci & Technol PRESTO, Chiyoda Ku, Tokyo 1020075, Japan

[3] Ctr Time Resolved Diffract, Dept Chem, Taejon 305701, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 46期

基金：

日本科学技术振兴机构;

关键词：

conducting materials; energy transfer; luminescence; mesoporous materials; organic frameworks;

D O I：

10.1002/anie.200803826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Blue belt: Condensation polymerization of pyrene (blue) and triphenylene (green) monomers leads to the formation of a hexagonal mesoporous covalent organic framework (see picture). This material exists in a belt shape, absorbs photons over a wide wavelength range to emit them as blue luminescence, and is semi-conducting, as well as being capable of repetitive on-off switching. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8826 / 8830

页数：5

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