Convenient construction of poly(3,4-ethylenedioxythiophene)-graphene pie-like structure with enhanced thermoelectric performance

被引：240

作者：

Xu, Kongli ^{[1
,2
,3
]}

Chen, Guangming ^{[1
,2
]}

Qiu, Dong ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, CAS Key Lab Green Printing, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 40期

基金：

中国国家自然科学基金;

关键词：

NANOCOMPOSITES; CONDUCTIVITY; THERMOPOWER; POLYANILINE; FILMS;

D O I：

10.1039/c3ta12691a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel strategy via the convenient construction of a pie-like structure has been developed to prepare a poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PEDOT-rGO) nanocomposite with a greatly enhanced thermoelectric performance. Via a template-directed in situ polymerization, thick and uniform coatings of PEDOT layers were conveniently grown on both sides of the rGO nanosheet surfaces due to a strong pi-pi interfacial interaction. The nanocomposite exhibited a significantly enhanced thermoelectric performance at room temperature with a power factor of 5.2 +/- 0.9 x 10(-6) W m(-1) K-2, greater than 13.3 times that of the PEDOT.

引用

页码：12395 / 12399

页数：5

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