Design rules for donors in bulk-heterojunction solar cells -: Towards 10 % energy-conversion efficiency

被引:4535
作者
Scharber, MC
Wühlbacher, D
Koppe, M
Denk, P
Waldauf, C
Heeger, AJ
Brabec, CL
机构
[1] Konarka Austria, A-4040 Linz, Austria
[2] Univ Calif Santa Barbara, Dept Mat Sci, Santa Barbara, CA 93106 USA
基金
美国国家科学基金会;
关键词
D O I
10.1002/adma.200501717
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For bulk-heterojunction photovoltaic cells fabricated from conjugated polymers and a fullerene derivative, the relation between the open-circuit voltage (V-oc) and the oxidation potential for different conjugated polymers is studied. A linear relation between V-oc and the oxidation potential is found (see figure). Based on this relation, the energy-conversion efficiency of a bulk-heterojunction solar cell is derived as a function of the bandgap and the energy levels of the conjugated polymer.
引用
收藏
页码:789 / +
页数:7
相关论文
共 27 条
  • [21] Recombination and loss analysis in polythiophene based bulk heterojunction photodetectors
    Schilinsky, P
    Waldauf, C
    Brabec, CJ
    [J]. APPLIED PHYSICS LETTERS, 2002, 81 (20) : 3885 - 3887
  • [22] Simulation of light intensity dependent current characteristics of polymer solar cells
    Schilinsky, P
    Waldauf, C
    Hauch, J
    Brabec, CJ
    [J]. JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) : 2816 - 2819
  • [23] Organic dye for highly efficient solid-state dye-sensitized solar cells
    Schmidt-Mende, L
    Bach, U
    Humphry-Baker, R
    Horiuchi, T
    Miura, H
    Ito, S
    Uchida, S
    Grätzel, M
    [J]. ADVANCED MATERIALS, 2005, 17 (07) : 813 - +
  • [24] High-performance polymer solar cells of an alternating polyfluorene copolymer and a fullerene derivative
    Svensson, M
    Zhang, FL
    Veenstra, SC
    Verhees, WJH
    Hummelen, JC
    Kroon, JM
    Inganäs, O
    Andersson, MR
    [J]. ADVANCED MATERIALS, 2003, 15 (12) : 988 - +
  • [25] Asymmetric tandem organic photovoltaic cells with hybrid planar-mixed molecular heterojunctions
    Xue, JG
    Uchida, S
    Rand, BP
    Forrest, SR
    [J]. APPLIED PHYSICS LETTERS, 2004, 85 (23) : 5757 - 5759
  • [26] Fluorene-based low band-gap copolymers for high performance photovoltaic devices
    Zhou, QM
    Hou, Q
    Zheng, LP
    Deng, XY
    Yu, G
    Cao, Y
    [J]. APPLIED PHYSICS LETTERS, 2004, 84 (10) : 1653 - 1655
  • [27] 2005, MRS B, V30, P1