Synthesis and coordination chemistry of perfluoroalkyl-derivatised triarylphosphites

被引：19

作者：

Adams, DJ ^{[1
]}

Gudmunsen, D ^{[1
]}

Fawcett, J ^{[1
]}

Hope, EG ^{[1
]}

Stuart, AM ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

TETRAHEDRON | 2002年 / 58卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

fluorous biphase; triaryl phosphite; platinum group metals; X-ray analysis;

D O I：

10.1016/S0040-4020(02)00208-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of ortho-, meta- and para-perfluoroalkyl-substituted triaryl phosphites have been prepared and their coordination chemistry investigated. Spectroscopic and structural data for the metal complexes indicate that, even with the additional oxygen spacer unit, complete electronic insulation of the phosphorus(III) centres is not achieved. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3827 / 3834

页数：8

共 39 条

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