Experimental study on the combustion sensitivity parameters and pre-combusted changes in functional groups of lignite coal dust

被引:67
作者
Cao, Weiguo [1 ,2 ]
Cao, Wei [3 ]
Peng, Yuhuai [1 ]
Qiu, Shanshan [1 ]
Miao, Nan [1 ]
Pan, Feng [1 ,2 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Natl Qual Supervis & Inspect Ctr Ind Explos Mat, Nanjing 210094, Jiangsu, Peoples R China
[3] China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Sichuan, Peoples R China
关键词
Lignite coal dust combustion; Sensitivity parameters; In-situ infrared spectrum; Diffuse reflection; Functional groups; IN-SITU FTIR; TEMPERATURE OXIDATION; HOT SURFACE; MECHANISM; PROPENSITY; EXPLOSIONS; ADSORPTION; IGNITION; BEHAVIOR; LAYER;
D O I
10.1016/j.powtec.2015.06.025
中图分类号
TQ [化学工业];
学科分类号
081705 [工业催化];
摘要
Sensitivity parameters are critical for safety management and risk assessment of coal dust combustion process. In this paper, in order to evaluate the combustion sensitivity parameters and reveal the mechanism of lignite coal dust, 20 L spherical explosion test apparatus and hot surface test apparatus were chosen to test the typical sensitivity parameters of lignite coal dust combustion. Results show that the limiting oxygen concentration of dust clouds (LOCC) was in the range of (13-14) %, and the minimum ignition temperature of dust layer (MITL) was in the range of (280-290) degrees C, respectively. The functional group variation law before combustion of lignite coal dust was tested by in-situ diffuse reflection Fourier transform infrared spectrometry (FTIR), and the proportions of functional groups in the lignite coal dust were analyzed from 30 degrees C to 290 degrees C. It is demonstrated that in coal dust combustion the key functional groups were -CH3/-CH2- and -OH. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:512 / 518
页数:7
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