Side Chain Engineering in Solution-Processable Conjugated Polymers

被引：939

作者：

Mei, Jianguo ^{[1
]}

Bao, Zhenan ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

来源：

CHEMISTRY OF MATERIALS | 2014年 / 26卷 / 01期

关键词：

conjugated polymers; side chain engineering; organic field-effect transistors; solar cells; THIN-FILM TRANSISTORS; FIELD-EFFECT TRANSISTORS; OPEN-CIRCUIT VOLTAGE; ORGANIC SOLAR-CELLS; PHOTOVOLTAIC PROPERTIES; HIGH-MOBILITY; SEMICONDUCTING POLYMERS; BAND-GAP; POLYTHIOPHENE DERIVATIVES; PHOTOPHYSICAL PROPERTIES;

D O I：

10.1021/cm4020805

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Side chains in conjugated polymers have been primarily utilized as solubilizing groups. However, these side chains have roles that are far beyond. We advocate using side chain engineering to tune a polymer's physical properties, including absorption, emission, energy level, molecular packing, and charge transport. To date, numerous flexible substituents suitable for constructing side chains have been reported. In this Perspective article, we advocate that the side chain engineering approach can advance better designs for next-generation conjugated polymers.

引用

页码：604 / 615

页数：12

共 169 条

[1] Effects of Odd-Even Side Chain Length of Alkyl-Substituted Diphenylbithiophenes on First Monolayer Thin Film Packing Structure [J].

Akkerman, Hylke B. ;

Mannsfeld, Stefan C. B. ;

Kaushik, Ananth P. ;

Verploegen, Eric ;

Burnier, Luc ;

Zoombelt, Arjan P. ;

Saathoff, Jonathan D. ;

Hong, Sanghyun ;

Atahan-Evrenk, Sule ;

Liu, Xueliang ;

Aspuru-Guzik, Alan ;

Toney, Michael F. ;

Clancy, Paulette ;

Bao, Zhenan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (30) :11006-11014

[2] Optically Active, Amphiphilic Poly(meta-phenylene ethynylene)s: Synthesis, Hydrogen-Bonding Enforced Helix Stability, and Direct AFM Observation of Their Helical Structures [J].

Banno, Motonori ;

Yamaguchi, Tomoko ;

Nagai, Kanji ;

Kaiser, Christian ;

Hecht, Stefan ;

Yashima, Eiji .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (20) :8718-8728

[3] Soluble and processable regioregular poly(3-hexylthiophene) for thin film field-effect transistor applications with high mobility [J].

Bao, Z ;

Dodabalapur, A ;

Lovinger, AJ .

APPLIED PHYSICS LETTERS, 1996, 69 (26) :4108-4110

[4] Soluble regioregular polythiophene derivatives as semiconducting materials for field-effect transistors [J].

Bao, ZN ;

Lovinger, AJ .

CHEMISTRY OF MATERIALS, 1999, 11 (09) :2607-2612

[5] Post-polymerization functionalization of conducting polymers: Novel poly(alkylthiophene)s substituted with easily replaceable activated ester groups [J].

Bauerle, P ;

Hiller, M ;

Scheib, S ;

Sokolowski, M ;

Umbach, E .

ADVANCED MATERIALS, 1996, 8 (03) :214-&

[6] Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications [J].

Beaujuge, Pierre M. ;

Frechet, Jean M. J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20009-20029

[7] Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices [J].

Beaujuge, Pierre M. ;

Reynolds, John R. .

CHEMICAL REVIEWS, 2010, 110 (01) :268-320

[8] Stretchable and self-healing polymers and devices for electronic skin [J].

Benight, Stephanie J. ;

Wang, Chao ;

Tok, Jeffrey B. H. ;

Bao, Zhenan .

PROGRESS IN POLYMER SCIENCE, 2013, 38 (12) :1961-1977

[9] Synthesis and Characterization of 5-Octylthieno[3,4-c]pyrrole-4,6-dione Derivatives As New Monomers for Conjugated Copolymers [J].

Berrouard, Philippe ;

Grenier, Francois ;

Pouliot, Jean-Remi ;

Gagnon, Eric ;

Tessier, Christian ;

Leclerc, Mario .

ORGANIC LETTERS, 2011, 13 (01) :38-41

[10] Self-assembly of regioregular, amphiphilic polythiophenes into highly ordered π-stacked conjugated polymer thin films and nanocircuits [J].

Bjornholm, T ;

Greve, DR ;

Reitzel, N ;

Hassenkam, T ;

Kjaer, K ;

Howes, PB ;

Larsen, NB ;

Bogelund, J ;

Jayaraman, M ;

Ewbank, PC ;

McCullough, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (30) :7643-7644

← 1 2 3 4 5 6 7 8 9 10 →