Highly enantioselective DNA-based catalysis

被引：158

作者：

Roelfes, G ^{[1
]}

Boersma, AJ ^{[1
]}

Feringa, BL ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst, Dept Organ Chem, Groningen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 06期

关键词：

D O I：

10.1039/b516552k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new approach to DNA-based asymmetric catalysis is presented, which gives rise to very high enantioselectivities (up to 99% ee) in the copper catalyzed Diets-Alder reaction in water.

引用

页码：635 / 637

页数：3

共 25 条

[1] CRYSTAL STRUCTURE OF IODIBOS-(2,2'-BIPYRIDYL)COPPER(II) IODIDE
BARCLAY, GA
KENNARD, CHL
HOSKINS, BF
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (DEC): : 5691 - &
[2] STRUCTURAL RESEARCH ON MIXED THIOCYANATE COPPER(II) COMPLEXES WITH MULTIDENTATE LIGANDS CONTAINING NITROGEN AS DONOR ATOM - CRYSTAL AND MOLECULAR-STRUCTURES OF ISOTHIOCYANATO[NN'-BIS(2-PYRIDYLMETHYLENE)TETRAMETHYLENEDIAMINE]COPPER(II) THIOCYANATE AND OF BIS(ISOTHIOCYANATO)[2-(2-PYRIDYL)BENZIMIDAZOLE]COPPER(II)C
BATTAGLIA, LP
BELICCHIFERRARI, M
BONAMARTINICORRADI, A
GASPARRIFAVA, G
PELIZZI, C
VIDONITANI, ME
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21): : 2197 - 2202
[3] Recognition and reaction of metallointercalators with DNA
Erkkila, KE
Odom, DT
Barton, JK
[J]. CHEMICAL REVIEWS, 1999, 99 (09) : 2777 - 2795
[4] A ribozyme for the aldol reaction
Fusz, S
Eisenführ, A
Srivatsan, SG
Heckel, A
Famulok, M
[J]. CHEMISTRY & BIOLOGY, 2005, 12 (08): : 941 - 950
[5] Directed evolution of nucleic acid enzymes
Joyce, GF
[J]. ANNUAL REVIEW OF BIOCHEMISTRY, 2004, 73 : 791 - 836
[6] Lu Y, 2002, CHEM-EUR J, V8, P4589
[7] Effects of Lewis acid-surfactant-combined catalysts on aldol and Diels-Alder reactions in water
Manabe, K
Mori, Y
Kobayashi, S
[J]. TETRAHEDRON, 1999, 55 (37) : 11203 - 11208
[8] Covalent Schiff base catalysis and turnover by a DNAzyme:: A M2+ independent AP-endonuclease mimic
May, JP
Ting, R
Lermer, L
Thomas, JM
Roupioz, Y
Perrin, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (13) : 4145 - 4156
[9] Design of copper DNA intercalators with leishmanicidal activity
Navarro, M
Cisneros-Fajardo, EJ
Sierralta, A
Fernández-Mestre, M
Silva, P
Arrieche, D
Marchán, E
[J]. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2003, 8 (04): : 401 - 408
[10] A systematic study of ligand effects on a Lewis-acid-catalyzed Diels-Alder reaction in water. Water-enhanced enantioselectivity
Otto, S
Engberts, JBFN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (29) : 6798 - 6806

← 1 2 3 →