A new class of self-assembly multinuclear Pt(II) coordination cages by a modular approach

被引:14
作者
Chand, DK [1 ]
Balaji, G [1 ]
Manivarman, R [1 ]
Athilakshmi, J [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
关键词
self-assembly; cage compounds; platinum; proton NMR;
D O I
10.1016/j.tetlet.2006.02.132
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The formation of three examples of a new class of self-assembly Pt(II) cage molecules of general formula [Pt-m(ligand)(n)]- (NO3)(2m) is achieved from Pt(II) and ligands. The compounds are observed in solution state and confirmed from the similarity of their proton NMR behavior as compared with that of reported Pd(II) compounds of the formula [Pd-m(ligand)(n)](NO3)(2m) (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2867 / 2869
页数:3
相关论文
共 12 条
[1]   Self-assembly by ligand-exchange reactions [J].
Chand, DK ;
Manivannan, R ;
Sahoo, HS ;
Jeyakumar, K .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (16) :3346-3352
[2]   Metal driven self-assembly of pyridine appended ligands with cis-protected/naked Pd(II) ion:: a comparative study [J].
Chand, DK ;
Fujita, M ;
Biradha, K ;
Sakamoto, S ;
Yamaguchi, K .
DALTON TRANSACTIONS, 2003, (13) :2750-2756
[3]   A molecular sphere of octahedral symmetry [J].
Chand, DK ;
Biradha, K ;
Fujita, M ;
Sakamoto, S ;
Yamaguchi, K .
CHEMICAL COMMUNICATIONS, 2002, (21) :2486-2487
[4]   Self-assembly of a novel macrotricyclic Pd(II) metallocage encapsulating a nitrate ion [J].
Chand, DK ;
Biradha, K ;
Fujita, M .
CHEMICAL COMMUNICATIONS, 2001, (17) :1652-1653
[5]   Coordination assemblies from a Pd(II)-cornered square complex [J].
Fujita, M ;
Tominaga, M ;
Hori, A ;
Therrien, B .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378
[6]   A MOLECULAR LOCK [J].
FUJITA, M ;
IBUKURO, F ;
YAMAGUCHI, K ;
OGURA, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (14) :4175-4176
[7]   Molecular paneling via coordination [J].
Fujita, M ;
Umemoto, K ;
Yoshizawa, M ;
Fujita, N ;
Kusukawa, T ;
Biradha, K .
CHEMICAL COMMUNICATIONS, 2001, (06) :509-518
[8]  
GILLARD RD, 1987, SYNTHESIS REACTIONS, V1, P311
[9]   Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].
Leininger, S ;
Olenyuk, B ;
Stang, PJ .
CHEMICAL REVIEWS, 2000, 100 (03) :853-907
[10]   High-symmetry coordination cages via self-assemhly [J].
Seidel, SR ;
Stang, PJ .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (11) :972-983