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Blends of semiconductor polymer and small molecular crystals for improved-performance thin-film transistors
被引:30
作者:

Russell, DM
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机构: Cambridge Res Lab Epson, Cambridge CB4 0FE, England

Newsome, CJ
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机构: Cambridge Res Lab Epson, Cambridge CB4 0FE, England

Li, SP
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机构: Cambridge Res Lab Epson, Cambridge CB4 0FE, England

Kugler, T
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机构: Cambridge Res Lab Epson, Cambridge CB4 0FE, England

Ishida, M
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机构: Cambridge Res Lab Epson, Cambridge CB4 0FE, England

Shimoda, T
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机构: Cambridge Res Lab Epson, Cambridge CB4 0FE, England
机构:
[1] Cambridge Res Lab Epson, Cambridge CB4 0FE, England
[2] Seiko Epson Corp, Technol Platform Res Ctr, Nagano 3990293, Japan
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D O I:
10.1063/1.2136356
中图分类号:
O59 [应用物理学];
学科分类号:
摘要:
Incorporating dihexyl-quarterthiophene (DH4T) into the active layer of a poly(3-hexylthiophene) thin-film transistor can enhance the mobility by a factor of 10. The DH4T concentration dependence shows the improvement in mobility is due to the formation of crystals within the blend film, which occur at a critical concentration of 29% DH4T. Application of percolation theory reveals that transport in blend devices is limited by the mobility of the poly (3-hexylthiophene)(P3HT) and by the crystal packing. With improved polymer performance, the mobility in blend films is expected to approach 1 cm(2)/V s. (c) 2005 American Institute of Physics.
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