Emerging sustainable technology for epoxidation directed toward plant oil-based plasticizers

被引：89

作者：

Chua, Seong-Chea ^{[1
]}

Xu, Xuebing ^{[1
]}

Guo, Zheng ^{[1
]}

机构：

[1] Aarhus Univ, Dept Engn, Dept Mol Biol, DK-8000 Aarhus C, Denmark

来源：

PROCESS BIOCHEMISTRY | 2012年 / 47卷 / 10期

关键词：

Sustainable plasticizer; Green technology; Epoxidation; Ionic liquids; Biocatalyst; Reaction specificity; HIGHLY ENANTIOSELECTIVE EPOXIDATION; FATTY METHYL-ESTERS; ANTARCTICA LIPASE-B; MN-SALEN CATALYST; CHEMOENZYMATIC EPOXIDATION; HYDROGEN-PEROXIDE; SOYBEAN OIL; ASYMMETRIC EPOXIDATION; OLEIC-ACID; ENZYMATIC-SYNTHESIS;

D O I：

10.1016/j.procbio.2012.05.025

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The chemical industry is increasingly looking toward sustainable technology to reduce the environmental impact and minimize the footprint of a chemical process. This work, which presents emerging technologies in academia and industry, discusses the development of advanced processes for the production Of epoxidized plant oil-based plasticizers. The effects of the substrate structure, oxygen-donor properties, catalysts and biocatalysts on the specificity of the epoxidation reaction are intensively discussed. The progress in enzymatic epoxidation and the application of neoteric media, such as ionic liquids, are also highlighted. Particular attention is given to understanding how the emerging processes, including the new catalysts and novel reaction systems, work to dictate the reaction efficiency and selectivity. Hence, this review will be of value for developing further improved processes. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：1439 / 1451

页数：13

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