Selective electrodesorption based atomic layer deposition (SEBALD) modifications of silver surfaces for enhancing oxygen reduction reaction activity

被引：8

作者：

Innocenti, M. ^{[1
,2
]}

Zangari, G. ^{[3
,4
]}

Zafferoni, C. ^{[1
]}

Bencista, I. ^{[1
]}

Becucci, L. ^{[1
]}

Lavacchi, A. ^{[2
]}

Di Benedetto, F. ^{[5
]}

Bellandi, S. ^{[1
]}

Vizza, F. ^{[2
]}

Foresti, M. L. ^{[1
]}

机构：

[1] Univ Florence, Dept Chem, I-50019 Sesto Fiorentino, FI, Italy

[2] CNR, ICCOM, I-50019 Sesto Fiorentino, FI, Italy

[3] Univ Virginia, Dept Mat Sci & Engn, Charlottesville, VA 22904 USA

[4] Univ Virginia, Ctr Elect Sci & Engn, Charlottesville, VA 22904 USA

[5] Univ Florence, Dept Earth Sci, I-50121 Florence, Italy

来源：

JOURNAL OF POWER SOURCES | 2013年 / 241卷

关键词：

ORR; SEBALD; Electrodeposition; Silver; catalytic surfaces; HEAT-TREATMENT; BIMETALLIC CATALYSTS; TERNARY CADMIUM; ZINC SULFIDES; IRON; ELECTROCATALYSTS; AG(111); ELECTRODEPOSITION; ELECTROREDUCTION; PARTICLES;

D O I：

10.1016/j.jpowsour.2013.04.111

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The increasing attention addressed toward the synergic effect of various metals on the catalysis of one of the most important electrocatalytic reaction, such as the Oxygen Reduction Reaction (ORR), led us to study the effect of monolayers of Fe and of mixed Fe and Co on Ag(111), whose catalytic activity is already known and well characterized. Fe and Co/Fe clusters were obtained by the Selective Electrodesorption Based Atomic Layer Deposition (SEBALD) method, which is a novel electrochemical route to deposit metal clusters on a foreign substrate recently proposed by our group. SEBALD of Fe or Co/Fe resulted in an enhanced catalytic activity; Co/Fe in particular was demonstrated to assemble in small clusters, providing access of the electrolyte to Ag and enabling a bimetallic catalytic effect. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：80 / 86

页数：7

共 47 条

[1]

Adzic R, 1998, FRONT ELECT, P197

[2] Single-site and nanosized Fe-Co electrocatalysts for oxygen reduction: Synthesis, characterization and catalytic performance [J].

Bambagioni, Valentina ;

Bianchini, Claudio ;

Filippi, Jonathan ;

Lavacchi, Alessandro ;

Oberhauser, Werner ;

Marchionni, Andrea ;

Moneti, Simonetta ;

Vizza, Francesco ;

Psaro, Rinaldo ;

Dal Santo, Vladimiro ;

Gallo, Alessandro ;

Recchia, Sandro ;

Sordelli, Laura .

JOURNAL OF POWER SOURCES, 2011, 196 (05) :2519-2529

[3] Novel carbon-supported Fe-N electrocatalysts synthesized through heat treatment of iron tripyridyl triazine complexes for the PEM fuel cell oxygen reduction reaction [J].

Bezerra, Cicero W. B. ;

Zhang, Lei ;

Lee, Kunchan ;

Liu, Hansan ;

Zhang, Jianlu ;

Shi, Zheng ;

Marques, Aldalea L. B. ;

Marques, Edmar P. ;

Wu, Shaohong ;

Zhang, Jiujun .

ELECTROCHIMICA ACTA, 2008, 53 (26) :7703-7710

[4] A review of Fe-N/C and Co-N/C catalysts for the oxygen reduction reaction [J].

Bezerra, Cicero W. B. ;

Zhang, Lei ;

Lee, Kunchan ;

Liu, Hansan ;

Marques, Aldalea L. B. ;

Marques, Edmar P. ;

Wang, Haijiang ;

Zhang, Jiujun .

ELECTROCHIMICA ACTA, 2008, 53 (15) :4937-4951

[5] A review of heat-treatment effects on activity and stability of PEM fuel cell catalysts for oxygen reduction reaction [J].

Bezerra, Cicero W. B. ;

Zhang, Lei ;

Liu, Hansan ;

Lee, Kunchan ;

Marques, Aldalea L. B. ;

Marques, Edmar P. ;

Wang, Haijiang ;

Zhang, Jiujun .

JOURNAL OF POWER SOURCES, 2007, 173 (02) :891-908

[6] Oxygen reduction on silver low-index single-crystal surfaces in alkaline solution:: Rotating ring DiskAg(hkl) studies [J].

Blizanac, BB ;

Ross, PN ;

Markovic, NM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (10) :4735-4741

[7]

Bockris J. O. M., 1993, SURFACE ELECTROCHEMI, P765

[8] Electrochemical Quartz Crystal Microbalauce Study of FeS Particles Attached to Au Surface [J].

Bura-Nakic, Elvira ;

Roka, Andras ;

Ciglenecki, Irena ;

Inzelt, Gyoergy .

ELECTROANALYSIS, 2009, 21 (15) :1699-1708

[9] Novel electrocatalysts for direct methanol fuel cells [J].

Chu, D ;

Jiang, RZ .

SOLID STATE IONICS, 2002, 148 (3-4) :591-599

[10] Development of electrocatalysts for solid alkaline fuel cell (SAFC) [J].

Coutanceau, C ;

Demarconnay, L ;

Lamy, C ;

Léger, JM .

JOURNAL OF POWER SOURCES, 2006, 156 (01) :14-19

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