Polymerization of equilibrium vesicles

被引：78

作者：

Morgan, JD ^{[1
]}

Johnson, CA ^{[1
]}

Kaler, EW ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM ENGN,CTR MOL ENGN & THERMODYNAM,NEWARK,DE 19711

来源：

LANGMUIR | 1997年 / 13卷 / 24期

关键词：

D O I：

10.1021/la970495e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spontaneous vesicles form in aqueous solutions of mixtures of cationic and anionic surfactants. Here we report that vesicles are also found in systems containing a polymerizable monomer as a fourth component and that these vesicles can be polymerized with retention of the equilibrium structure. This is a convenient and versatile approach in which the vesicle architecture can be controlled by equilibrium surfactant self-assembly prior to polymerization, while the microstructure of the spherical polymer network can be controlled by the choice of monomer and degree of cross-linking.

引用

页码：6447 / 6451

页数：5

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