Atroposelectivity in the reactions of ortholithiated aromatic tertiary amides with aldehydes

被引：84

作者：

Bowles, P ^{[1
]}

Clayden, J ^{[1
]}

Helliwell, M ^{[1
]}

McCarthy, C ^{[1
]}

Tomkinson, M ^{[1
]}

Westlund, N ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 17期

关键词：

D O I：

10.1039/a701671i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The products of the addition of ortholithiated N,N-dialkylnaphthamides to aldehydes are pairs of stable,diastereoisomeric atropisomers, formed with selectivities of up to 90:10 in favour bf the syn-atropisomer.

引用

页码：2607 / 2616

页数：10

共 69 条

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