(2,2'-bipyridine-N,N')(mu-thiosulfato)-cadmium(II)

被引：15

作者：

Baggio, S

Pardo, MI

Baggio, R

Garland, MT

机构：

[1] CENPAT,CONICET,RA-9120 PUERTO MADRYN,CHUBUT,ARGENTINA

[2] COMIS NACL ENERGIA ATOM,DEPT FIS,RA-1429 BUENOS AIRES,DF,ARGENTINA

[3] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT FIS,SANTIAGO,CHILE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197001972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title Cd-II complex, [Cd(S2O3)(C10H8N2)], consists of polymeric chains running along the monoclinic symmetry axis. The elementary units are defined by pentacoordinated Cd-II atoms bonded to three different thiosulfate groups and a bidentate bipyridine ligand. The bridging thiosulfates bind metal centres through two different sequences, Cd1-S1-Cd1' and Cd1-O1'-S2'-S1'-Cd1', thus defining a six-membered ring. Individual chains are held together solely via van der Waals interactions.

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页码：727 / 729

页数：3

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