Bis(mu-thiosulfato)-1 kappa O,1:2 kappa S-2;2 kappa O,1:2 kappa S-2-bis[(2,9-dimethyl-1,10-phenanthroline-N,N')cadmium(II)]

被引：14

作者：

Baggio, R

Baggio, S

Pardo, MI

Garland, MT

机构：

[1] UNIV NACL PATAGONIA,RA-1920 SEDE PUERTO MADRY,CHUBUT,ARGENTINA

[2] CONSEJO NACL INVEST CIENT & TECN,CENPAT,RA-9120 PUERTO MADRYN,CHUBUT,ARGENTINA

[3] UNIV CHILE,FAC CIENCIAS FIS & MATEMAT,DEPT FIS,SANTIAGO,CHILE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷 / pt 8期

关键词：

D O I：

10.1107/S0108270196003502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [Cd-2(S2O3)(2)(C14H12N2)(2)], presents a dimeric structure with the novel feature of having the thiosulfate group acting as both a bridging and a bidentate ligand. This unusual coordination mode leads to an S-S bond length in the mid-range of those found in the S-bridging thiosulfates, but longer than those observed in monodentate S-bonded complexes. The pentacoordinate Cd-II center exhibits a distorted environment.

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页码：1939 / 1942

页数：4

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