Toluene-assisted synthesis of RHO-type zeolitic imidazolate frameworks: synthesis and formation mechanism of ZIF-11 and ZIF-12

被引：141

作者：

He, Ming ^{[1
,2
]}

Yao, Jianfeng ^{[2
]}

Liu, Qi ^{[2
]}

Zhong, Zhaoxiang ^{[2
]}

Wang, Huanting ^{[2
]}

机构：

[1] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Jiangsu, Peoples R China

[2] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 47期

基金：

澳大利亚研究理事会;

关键词：

METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE CAPTURE; ADSORPTION; MEMBRANE; WATER;

D O I：

10.1039/c3dt52103f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Toluene was discovered as the structure template for the synthesis of large-cage RHO-type zeolitic imidazolate frameworks (ZIF-11 and ZIF-12) in an alcohol-based solution where benzimidazole-toluene interactions play a decisive structure-directing role; otherwise it leads to small-cage SOD-type ZIF-7 and ZIF-9 without toluene. The specific pi-pi interactions make toluene molecules adopt a specific and oriented arrangement in the unit cell. XRD intensity of the (100) plane is strongly dependent on the amount of toluene: apparent intensity degradation is observed after removing toluene by solvent exchange or thermal treatment, and the peak intensity is recoverable by filling of the pores with toluene vapor. More-polar methanol as compared to ethanol is favorable for the formation of RHO-type ZIFs due to the enhanced interactions between toluene and imidazolate linkers.

引用

页码：16608 / 16613

页数：6

共 31 条

[1] Guest-induced gate-opening of a zeolite imidazolate framework [J].

Aguado, Sonia ;

Bergeret, Gerard ;

Titus, Marc Pera ;

Moizan, Virginie ;

Nieto-Draghi, Carlos ;

Bats, Nicolas ;

Farrusseng, David .

NEW JOURNAL OF CHEMISTRY, 2011, 35 (03) :546-550

[2] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[3] Oriented Zeolitic Imidazolate Framework-8 Membrane with Sharp H2/C3H8 Molecular Sieve Separation [J].

Bux, Helge ;

Feldhoff, Armin ;

Cravillon, Janosch ;

Wiebcke, Michael ;

Li, Yan-Shuo ;

Caro, Juergen .

CHEMISTRY OF MATERIALS, 2011, 23 (08) :2262-2269

[4] Flexibility and swing effect on the adsorption of energy-related gases on ZIF-8: combined experimental and simulation study [J].

Fairen-Jimenez, David ;

Galvelis, Raimondas ;

Torrisi, Antonio ;

Gellan, Alistair D. ;

Wharmby, Michael T. ;

Wright, Paul A. ;

Mellot-Draznieks, Caroline ;

Dueren, Tina .

DALTON TRANSACTIONS, 2012, 41 (35) :10752-10762

[5] Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal-Organic Framework ZIF-7 through a Gate-Opening Mechanism [J].

Gucuyener, Canan ;

van den Bergh, Johan ;

Gascon, Jorge ;

Kapteijn, Freek .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (50) :17704-17706

[6] The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities [J].

Hafizovic, Jasmina ;

Bjorgen, Morten ;

Olsbye, Unni ;

Dietzel, Pascal D. C. ;

Bordiga, Silvia ;

Prestipino, Carmelo ;

Lamberti, Carlo ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) :3612-3620

[7] Zeolitic Imidazolate Frameworks as H2 Adsorbents: Ab Initio Based Grand Canonical Monte Carlo Simulation [J].

Han, Sang Soo ;

Choi, Seung-Hoon ;

Goddard, William A., III .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (27) :12039-12047

[8] Zeolite a imidazolate frameworks [J].

Hayashi, Hideki ;

Cote, Adrien P. ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

NATURE MATERIALS, 2007, 6 (07) :501-506

[9] Synthesis of Zeolitic Imidazolate Framework-7 in a Water/Ethanol Mixture and Its Ethanol-Induced Reversible Phase Transition [J].

He, Ming ;

Yao, Jianfeng ;

Li, Lunxi ;

Wang, Kun ;

Chen, Fanyan ;

Wang, Huanting .

CHEMPLUSCHEM, 2013, 78 (10) :1222-1225

[10] Aqueous solution synthesis of ZIF-8 films on a porous nylon substrate by contra-diffusion method [J].

He, Ming ;

Yao, Jianfeng ;

Li, Lunxi ;

Zhong, Zhaoxiang ;

Chen, Fanyan ;

Wang, Huanting .

MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 179 :10-16

← 1 2 3 4 →