Guest-induced gate-opening of a zeolite imidazolate framework

被引：165

作者：

Aguado, Sonia ^{[1
]}

Bergeret, Gerard ^{[1
]}

Titus, Marc Pera ^{[1
]}

Moizan, Virginie ^{[2
]}

Nieto-Draghi, Carlos ^{[3
]}

Bats, Nicolas ^{[2
]}

Farrusseng, David ^{[1
]}

机构：

[1] Univ Lyon, CNRS, IRCELYON, F-69626 Villeurbanne, France

[2] IFP Energies Nouvelles, Phys & Anal Div, F-69360 Solaize, France

[3] IFP Energies Nouvelles, Thermodynam & Mol Simulat Dept, F-92852 Rueil Malmaison, France

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 03期

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION-POLYMER; HENRYS REGION; ADSORPTION; CO2; MOLECULES; NETWORK; MIL-53; GASES;

D O I：

10.1039/c0nj00836b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The zinc benzimidazolate coordination polymer (ZIF-7) shows a reversible gate-opening effect upon variation of partial pressure of CO2 or temperature. This phenomenon, which is unique for a MOF with sodalite topology, arises from a phase-to-phase transformation upon guest adsorption-desorption.

引用

页码：546 / 550

页数：5

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