Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies

被引:1568
作者
Huang, XC
Lin, YY
Zhang, JP
Chen, XM [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China
[2] Shantou Univ, Dept Chem, Guangzhou 515063, Peoples R China
关键词
bridging ligands; crystal engineering; N ligands; zeolite analogues; zinc;
D O I
10.1002/anie.200503778
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Thermally robust porous metal-organic frameworks (MOFs) with zeolitic topologies were constructed by means of a ligand-directed strategy involving molecular tailoring of simple bridging imidazolates with coordinatively unimportant substituents. This led to the isolation of three new MOFs having unusually high symmetries, intriguing topologies such as the supercage shown in the picture, and high thermal stability. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1557 / 1559
页数:3
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