Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies

被引：1568

作者：

Huang, XC

Lin, YY

Zhang, JP

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

[2] Shantou Univ, Dept Chem, Guangzhou 515063, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期

关键词：

bridging ligands; crystal engineering; N ligands; zeolite analogues; zinc;

D O I：

10.1002/anie.200503778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Thermally robust porous metal-organic frameworks (MOFs) with zeolitic topologies were constructed by means of a ligand-directed strategy involving molecular tailoring of simple bridging imidazolates with coordinatively unimportant substituents. This led to the isolation of three new MOFs having unusually high symmetries, intriguing topologies such as the supercage shown in the picture, and high thermal stability. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1557 / 1559

页数：3

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