Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies

被引：1568

作者：

Huang, XC

Lin, YY

Zhang, JP

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China

[2] Shantou Univ, Dept Chem, Guangzhou 515063, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期

关键词：

bridging ligands; crystal engineering; N ligands; zeolite analogues; zinc;

D O I：

10.1002/anie.200503778

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Thermally robust porous metal-organic frameworks (MOFs) with zeolitic topologies were constructed by means of a ligand-directed strategy involving molecular tailoring of simple bridging imidazolates with coordinatively unimportant substituents. This led to the isolation of three new MOFs having unusually high symmetries, intriguing topologies such as the supercage shown in the picture, and high thermal stability. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1557 / 1559

页数：3

共 44 条

[31]

1442::AID-ANGE1442ANDGT

[32]

3.0.CO

[33]

2-4, 10.1002/1521-3757(20020415)114:8%3C1442::AID-ANGE1442%3E3.0.CO

[34]

2-4]

[35]

Tian YQ, 2002, ANGEW CHEM INT EDIT, V41, P1384, DOI 10.1002/1521-3773(20020415)41:8<1384::AID-ANIE1384>3.0.CO

[36]

2-6

[37] [CuI(im)]∞:: Is this air-stable copper(I) imidazolate (8210)-net polymer the species responsible for the corrosion-inhibiting properties of imidazole with copper metal? [J].

Tian, YQ ;

Xu, HJ ;

Weng, LH ;

Chen, ZX ;

Zhao, DY ;

You, XZ .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (09) :1813-1816

[38] Two polymorphs of cobalt(II) imidazolate polymers synthesized solvothermally by using one organic template N,N-dimethylacetamide [J].

Tian, YQ ;

Chen, ZX ;

Weng, LH ;

Guo, HB ;

Gao, S ;

Zhao, DY .

INORGANIC CHEMISTRY, 2004, 43 (15) :4631-4635

[39] The silica-like extended polymorphism of cobalt(II) imidazolate three-dimensional frameworks: X-ray single-crystal structures and magnetic properties [J].

Tian, YQ ;

Cai, CX ;

Ren, XM ;

Duan, CY ;

Xu, Y ;

Gao, S ;

You, XZ .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (22) :5673-5685

[40] Entangled coordination networks with inherent features of polycatenation, polythreading, and polyknotting [J].

Wang, XL ;

Qin, C ;

Wang, EB ;

Li, YG ;

Su, ZM ;

Xu, L ;

Carlucci, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (36) :5824-5827

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