[CuI(im)]∞:: Is this air-stable copper(I) imidazolate (8210)-net polymer the species responsible for the corrosion-inhibiting properties of imidazole with copper metal?

被引：33

作者：

Tian, YQ

Xu, HJ

Weng, LH

Chen, ZX

Zhao, DY

You, XZ ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Coordinat Chem Inst, Nanjing 210093, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[3] Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 09期

关键词：

coordination polymers; copper; heterocycles; N ligands; solvothermal synthesis;

D O I：

10.1002/ejic.200300920

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An air-stable two-dimensional (2D) copper(i) imidazolate polymer, [Cu-1(im)](x) (1), with a d(10)-d(10) interaction, was synthesized solvothermally and structurally characterized by Xray crystallography: alpha = 8.069(2), b = 8.068(2), c = 13.425(3) Angstrom,beta = 99.414(3)degrees, monoclinic, C2/c. This is the first example of an air-stable copper(i) imidazolate polymer that may play a significant role in the corrosion- inhibition mechanism of imidazole (or its derivatives) with copper metal. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

引用

页码：1813 / 1816

页数：4

共 23 条

[1] SURFACE ENHANCED RAMAN-SCATTERING AND IMPEDANCE STUDIES ON THE INHIBITION OF COPPER CORROSION IN SULFATE-SOLUTIONS BY 5-SUBSTITUTED BENZOTRIAZOLES [J].