A metal-organic framework with the zeolite MTN topology containing large cages of volume 2.5 nm3

被引:232
作者
Fang, QR
Zhu, GS [1 ]
Xue, M
Sun, JY
Wei, Y
Qiu, SL
Xu, RR
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
[2] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA
关键词
cadmium; coordination polymers; organic-inorganic hybrid composites; zeolite analogues;
D O I
10.1002/anie.200462260
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) If you look for holes, you will find them in a novel 3D metal-organic framework complex with zeolite MTN topology. The framework of [{Cd(H2O)3}34-(N4C 6H12)17]Cl68·46 H 2O·68 DMF greatly expands the original structure of MTN and contains large cages with a volume of about 2522 Å3 (see structure). MTN = zeolite socony mobil - thirty-nine, DMF = N,N- dimethylformamide. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3845 / 3848
页数:4
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