A metal-organic framework with the zeolite MTN topology containing large cages of volume 2.5 nm3

被引：232

作者：

Fang, QR

Zhu, GS ^{[1
]}

Xue, M

Sun, JY

Wei, Y

Qiu, SL

Xu, RR

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 25期

关键词：

cadmium; coordination polymers; organic-inorganic hybrid composites; zeolite analogues;

D O I：

10.1002/anie.200462260

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) If you look for holes, you will find them in a novel 3D metal-organic framework complex with zeolite MTN topology. The framework of [{Cd(H2O)3}34-(N4C 6H12)17]Cl68·46 H 2O·68 DMF greatly expands the original structure of MTN and contains large cages with a volume of about 2522 Å3 (see structure). MTN = zeolite socony mobil - thirty-nine, DMF = N,N- dimethylformamide. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3845 / 3848

页数：4