A novel approach to electrically and thermally conductive elastomers using graphene

被引:187
作者
Araby, Sherif [1 ,4 ]
Zhang, Liqun [2 ]
Kuan, Hsu-Chiang [3 ]
Dai, Jia-Bin [1 ]
Majewski, Peter [1 ]
Ma, Jun [1 ,2 ]
机构
[1] Univ S Australia, Sch Engn, Mawson Lakes, SA 5095, Australia
[2] Beijing Univ Chem Technol, Key Lab Nanomat, Minist Educ, Beijing 100029, Peoples R China
[3] Far East Univ, Dept Energy Applicat Engn, Tainan 744, Taiwan
[4] Benha Univ, Dept Mech Engn, Fac Engn, Cairo, Egypt
关键词
Graphene; Elastomers; Composites; MECHANICAL-PROPERTIES; NANOCOMPOSITES; COMPOSITES; INTERFACE; COPOLYMER; PLATELETS; LAYERS;
D O I
10.1016/j.polymer.2013.05.014
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
Electrically and thermally conductive elastomers are highly desired in industries, since they can prevent static electricity accumulation and reduce internal heat build-up. Previous methodologies using carbon black, metal nanoparticles and carbon nanotubes are either ineffective or expensive. By contrast, we in this study developed electrically and thermally conductive, high-mechanical performance elastomers, by adopting cost-effective, high-structural integrity graphene platelets (GnPs) of 3.55 +/- 0.32 nm in thickness and employing an industrial compatible method. A percolation threshold of electrical conductivity was observed at 16.5 vol% GnPs, and the elastomer thermal conductivity improved 240% at 41.6 vol%. At 24 vol%, tensile strength, Young's modulus, and tear strength improved 230%, 506% and 445%, respectively. By comparing the reinforcement effect of GnPs with those of carbon black, multi-walled carbon nanotubes and silicate layers, we found that GnPs are a promising candidate for developing cost-effective, functional, high-mechanical performance elastomers. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3663 / 3670
页数:8
相关论文
共 50 条
[1]
Addou R., 2012, APPL PHYS LETT, V100
[2]
Bagri A, 2010, NAT CHEM, V2, P581, DOI [10.1038/nchem.686, 10.1038/NCHEM.686]
[3]
Balandin AA, 2011, NAT MATER, V10, P569, DOI [10.1038/nmat3064, 10.1038/NMAT3064]
[4]
Mechanical behavior of particle filled elastomers [J].
Bergström, JS ;
Boyce, MC .
RUBBER CHEMISTRY AND TECHNOLOGY, 1999, 72 (04) :633-656
[5]
Multiwall carbon nanotube elastomeric composites: A review [J].
Bokobza, Liliane .
POLYMER, 2007, 48 (17) :4907-4920
[6]
Bréchet Y, 2001, ADV ENG MATER, V3, P571, DOI 10.1002/1527-2648(200108)3:8<571::AID-ADEM571>3.0.CO
[7]
2-M
[8]
Chazeau L, 2010, MECH PROPERTIES RUBB, P291
[9]
Preparation and characterization of graphite nanosheets from ultrasonic powdering technique [J].
Chen, GH ;
Weng, WG ;
Wu, DJ ;
Wu, CL ;
Lu, JR ;
Wang, PP ;
Chen, XF .
CARBON, 2004, 42 (04) :753-759
[10]
Emtsev KV, 2009, NAT MATER, V8, P203, DOI [10.1038/nmat2382, 10.1038/NMAT2382]