共 33 条
Solid-state solar modules based on mesoscopic organometal halide perovskite: a route towards the up-scaling process
被引:162
作者:
Matteocci, F.
[1
]
Razza, S.
Di Giacomo, F.
[1
]
Casaluci, S.
[1
]
Mincuzzi, G.
[1
]
Brown, T. M.
[1
]
D'Epifanio, A.
[2
]
Licoccia, S.
[2
]
Di Carlo, A.
[1
]
机构:
[1] Univ Roma Tor Vergata, CHOSE, Dept Elect Engn, I-00133 Rome, Italy
[2] Univ Roma Tor Vergata, Dept Chem Sci & Technol, I-00133 Rome, Italy
关键词:
CELLS;
EFFICIENCY;
MECHANISM;
TIO2;
DEVICE;
D O I:
10.1039/c3cp55313b
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
We fabricated the first solid state modules based on organometal halide perovskite CH3NH3PbI3-xClx using Spiro-OMeTAD and poly-(3-hexylthiophene) as hole transport materials. Device up-scaling was performed using innovative procedures to realize large-area cells and the integrated series-interconnections. The perovskite-based modules show a maximum conversion efficiency of 5.1% using both poly(3-hexylthiophene) and Spiro-OMeTAD. A long-term stability test was performed (in air, under AM1.5G, 1 Sun illumination conditions) using both materials showing different behaviour under continuous light stress. Whilst the poly(3-hexylthiophene)-based module efficiency drops by about 80% with respect to the initial value after 170 hours, the Spiro-based module shows a promising long-term stability maintaining more than 60% of its initial efficiency after 335 hours.
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页码:3918 / 3923
页数:6
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