Synthesis, characterization, and X-ray crystal structure of a gallium monohydroxide and a hetero-bimetallic gallium zirconium oxide

被引：42

作者：

Singh, S ^{[1
]}

Jancik, V ^{[1
]}

Roesky, HW ^{[1
]}

Herbst-Irmer, R ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 03期

关键词：

D O I：

10.1021/ic051769l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A monomeric hydroxide of gallium, LGa(Me)OH, containing terminal hydroxide and methyl groups was prepared by the hydrolysis of LGa(Me)Cl in the presence of N-heterocyclic carbene and water [L = HC{(CMe)(2,6-i-Pr2C6H3N)}(2)] in high yield and in a pure form. LGa(Me)OH was used as a synthon to assemble the first hetero-bimetallic compound with a Ga-O-Zr core, [(LGaMe)-(Cp2ZrMe)](u-O).

引用

页码：949 / 951

页数：3

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