Synthesis, structural characterization, and reaction of the first terminal hydroxide-containing alumoxane with an [{Al(OH)}2(μ-O)] core

被引：68

作者：

Bai, GC ^{[1
]}

Roesky, HW ^{[1
]}

Li, JY ^{[1
]}

Noltemeyer, M ^{[1
]}

Schmidt, HG ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 44期

关键词：

aluminum; ammonia; biphasic system; hydrolysis; hydroxide;

D O I：

10.1002/anie.200352163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Towards new polymerization-catalyst activators: A new synthetic approach is described for the hitherto unknown [{LAI(OH)}2(μ-O)]·0. 5 (C7H8)·C6H14 species (1; L = HC[(CMe)(2,6-iPr2C6H3N)]2). Further reaction of the Brönsted acidic OH groups of 1 with Me 2AlH results in the formation of trimeric alumoxane containing a three coordinate Al center [(LAI)2-(MeAl)(μ-O) 3]·2 C7H8, the core of which is depicted. These compounds may have use as activators for olefin-polymerization catalysts.

引用

页码：5502 / 5506

页数：5

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