Synthesis of the first compound with a rhombohedral Ti6(μ3-NH)6(μ3-N)2 core structure by ammonolysis of a titanium chelate in a two-phase system

被引：26

作者：

Bai, GC ^{[1
]}

Roesky, HW ^{[1
]}

Noltemeyer, M ^{[1
]}

Hao, HJ ^{[1
]}

Schmidt, HG ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 15期

关键词：

D O I：

10.1021/om0001927

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [{p-MeC6H4C(NSiMe3)(2)}(2)TiCl2] (1) with NaNH2 gave the novel titanium aggregate [{p-MeC6H4C(NSiMe3)(2)Ti}(6)(mu(3)-NH)(6)(mu(3)-N)(2). 6C(7)H(8)] (2). Treatment of 1 with potassium in liquid ammonia and toluene produced the titanium(III) complex [{p-MeC6H4C(NSiMe3)(2)}(3)Ti] (3). Compound 2 contains the largest Ti-N core so far reported.

引用

页码：2823 / 2825

页数：3

共 15 条

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